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A Focus on Triazolium as a Multipurpose Molecular Station
Katarzyna Eichstaedt Javier Jaramillo-Garcia David A. Leigh Vanesa Marcos Simone Pisano Thomas A. Singleton Switching between Anion-Binding Catalysis and Aminocatalysis with a Rotaxane Dual-Function Catalyst Journal of the American Chemical Society
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The long and the short of it A bistable molecular muscle based on a doubly threaded Janus‐type 2 rotaxane is assembled using a template‐directed self‐assembly process.Under the influence of changes in the pH value the two identical matching components glide along one another through terminal crown ether moieties bringing about expansion and contraction of the molecule.
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May 20 2008 · A glycorotaxane molecular machine The mannosyl 2 rotaxane shuttle contains an original triazolium station an anilinium station and a mannoside stopper.The mild synthesis of the 2 rotaxane can be carried out by a templated approach using a two‐step sequence 1) "click chemistry" and 2) N‐methylation of the 1 2 3‐triazole.
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